Abstract
Samples of PrL(CH3C00)2Cl-nH20 ( L=2,7J3,1S,-tetremethyl- 3,6, 1 4, 1 7,23,24-hexaazatricycloi 1 7.3. 1 .18'12] tetracosa-1(23), 2, 6, 8, 10, 12(24), 13, 17, 19, 21-decaene) were tested as lanthanide shift reagents using 1-heptanol, diisopropyl amine and hexylamine as substrates. These tests were unsuccessful. Syntheses of similar compounds with nitrate, carbonate, picrate, and chloroacetate counteranions were attempted in our desire to prepare template complexes with displeceable counteranions. A successful lanthanide shift reagent has not yet been synthesized.
Library of Congress Subject Headings
Lanthanide shift reagents--Testing; Nuclear magnetic resonance spectroscopy; Rare earth metal compounds
Publication Date
7-1-1989
Document Type
Thesis
Department, Program, or Center
School of Chemistry and Materials Science (COS)
Advisor
Name Illegible
Recommended Citation
DiSano, Mary, "Characterization and 1H-NMR applications of hexaaza macrocyclic complexes of lanthanides" (1989). Thesis. Rochester Institute of Technology. Accessed from
https://repository.rit.edu/theses/5996
Campus
RIT – Main Campus
Comments
Note: imported from RIT’s Digital Media Library running on DSpace to RIT Scholar Works. Physical copy available through RIT's The Wallace Library at: QD77 .D574 1989