Abstract
This thesis evaluates clean hydrogen production pathways suitable for the United Arab Emirates by integrating nuclear, solar, and wind energy with proton exchange membrane electrolysis (PEM), anion exchange membrane electrolysis with a liquid alkaline separator (AEM), and alkaline water electrolysis (AWE). A literature review was first conducted to compare hydrogen production technologies based on efficiency, cost, scalability, environmental performance, and compatibility with UAE energy resources. Energy and exergy models were then developed for the APR1400 steam Rankine cycle, the Mohammed bin Rashid Al Maktoum Solar Park, the Sir Bani Yas wind farm, and the three electrolysis technologies. The APR1400 Rankine-cycle mass-flow-rate model showed strong agreement with manufacturer data, with a maximum deviation of 2.12%. The calculated source-side exergy efficiencies were 78.47% for the APR1400 Rankine cycle, 52.16% for the wind-energy system, and 12.97% for the representative solar PV system. At 60°C and 1 bar, PEM achieved a voltage efficiency of 67.08%, followed by AWE at 65.38% and AEM with a liquid alkaline separator at 38.47%. For the detailed PEM integrated pathways, the overall exergy efficiencies were 51.12% for Nuclear-PEM, 33.98% for Wind-PEM, and 11.48% for Solar-PEM. The Nuclear-PEM pathway was treated as the detailed integrated benchmark case, while the source-coupled AEM and AWE pathway results were generated as screening-level extensions using the same source-side boundaries and electrolysis conversion factors rather than full benchmark-detail subsystem models. The power-based Sankey analysis showed that the wind pathways achieved high source-to-hydrogen efficiencies, while the solar pathways produced the largest absolute hydrogen output because of the large installed solar capacity. A normalized 1 MW cost model showed that PEM had the lowest levelized cost of hydrogen. The calculated LCOH was $3.93/kg H₂ for solar- and nuclear-powered PEM and $4.36/kg H₂ for wind-powered PEM. None of the evaluated cases reached the grey-hydrogen benchmark of $1.52/kg H₂ under the stated assumptions. The results indicate that clean hydrogen production in the UAE is technically promising, but competitiveness requires lower clean-electricity prices, reduced capital and operating costs, improved electrolyzer efficiency and durability, and deployment at larger scales
Publication Date
7-2026
Document Type
Thesis
Student Type
Graduate
Degree Name
Mechanical Engineering (MS)
Advisor
Mohammed Abdulrahman
Advisor/Committee Member
Pablo Izquierdo Lopez
Advisor/Committee Member
Umer Javed
Recommended Citation
Kewalramani, Gaurav CJK, "Exergy Analyses of Potential Clean Hydrogen Technologies in the UAE" (2026). Thesis. Rochester Institute of Technology. Accessed from
https://repository.rit.edu/theses/12721
Campus
RIT Dubai

Comments
This thesis has been embargoed. The full-text will be available on or around 8/6/2027.